Effect of Solvent Selectivity on Chain Exchange Kinetics in Block Copolymer Micelles
Abstract
The effect of solvent selectivity on the chain exchange kinetics for two polystyrene-b-poly(ethylene-alt-propylene) block copolymer micelles (SEP 26–70 and SEP 42–64, where the numbers denote the molecular weight of each block in kg/mol) was investigated in pure squalane and in binary mixed solvents of squalane and 1-phenyldodecane, using time-resolved small-angle neutron scattering (TR-SANS). The exchange rate accelerates by 5 orders of...
Paper Details
Title
Effect of Solvent Selectivity on Chain Exchange Kinetics in Block Copolymer Micelles
Published Date
Dec 19, 2019
Journal
Volume
53
Issue
1
Pages
417 - 426
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