Original paper

Chameleon-like Behavior of the Directing Group in the Rh(III)-Catalyzed Regioselective C–H Amidation of Indole: An Experimental and Computational Study

Volume: 9, Issue: 11, Pages: 10233 - 10244
Published: Oct 1, 2019
Abstract
The Rh(III)-catalyzed regioselective C–H amidation of N-methoxy-1H-indole-1-carboxamides by 1,4,2-dioxazol-5-ones was studied. N-Methoxy amide, the directing group (DG) of interest, undergoes four different transformations through DG-retained, -coupled, -eliminated, or -migrated processes under moderately varied reaction conditions. Solvents, additives, and temperature play important roles in these selective transformations; a trace addition of...
Paper Details
Title
Chameleon-like Behavior of the Directing Group in the Rh(III)-Catalyzed Regioselective C–H Amidation of Indole: An Experimental and Computational Study
Published Date
Oct 1, 2019
Volume
9
Issue
11
Pages
10233 - 10244
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