Effect of Polymer Chemistry on Chain Conformations in Hairy Nanoparticle Assemblies

Matrix-free, polymer-grafted nanoparticles, called hairy nanoparticle assemblies (aHNPs), have proven advantageous over traditional nanocomposites, as good dispersion and structural order can be achieved. Recent studies have shown that conformational changes in the polymer structure can lead to significant enhancements in the mechanical properties of aHNPs. To quantify how polymer chemistry affects the chain conformations in aHNPs, here we...