Original paper

Triggered Gate Opening and Breathing Effects during Selective CO2 Adsorption by Merlinoite Zeolite

Volume: 141, Issue: 32, Pages: 12744 - 12759
Published: Aug 2, 2019
Abstract
Zeolites with flexible structures that adapt to coordinate extraframework cations when dehydrated show a rich variety of gas adsorption behavior and can be tuned to optimize kinetics and selectivity. Merlinoite zeolite (topology type MER) with Si/Al = 3.8 has been prepared in Na, K, and Cs forms and its structural response to dehydration measured: the unit cell volumes decrease by 9.8%, 7.7%, and 7.1% for Na-, K-, and Cs-MER, respectively....
Paper Details
Title
Triggered Gate Opening and Breathing Effects during Selective CO2 Adsorption by Merlinoite Zeolite
Published Date
Aug 2, 2019
Volume
141
Issue
32
Pages
12744 - 12759
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