Titanium

Endocrinology

Catalysis

Physical chemistry

Engineering

Chemical engineering

Medicine

Oxide

Optoelectronics

Biochemistry

Nanotechnology

Electrode

Heterojunction

Anode

Surface engineering

Titanium oxide

Lithium (medication)

Chemistry

Metallurgy

Materials science

Electrochemistry

Advanced Energy Materials

The altering of electronic states of metal oxides offers a promising opportunity to realize high‐efficiency surface catalysis, which play a key role in regulating polysulfides (PS) redox in lithium–sulfur (Li–S) batteries. However, little effort has been devoted to understanding the relationship between the electronic state of metal oxides and a catalyst's properties in Li–S cells. Herein, defect‐rich heterojunction electrocatalysts composed of ultrathin TiO 2‐ x nanosheets and carbon nanotubes (CNTs) for Li–S batteries are reported. Theoretical simulations indicate that oxygen vacancies and heterojunction can enhance electronic conductivity and chemical adsorption. Spectroscopy and electrochemical techniques further indicate that the rich surface vacancies in TiO 2‐ x nanosheets result in highly activated trapping sites for LiPS and lower energy barriers for fast Li ion mobility. Meanwhile, the redistribution of electrons at the heterojunction interfaces realizes accelerated surface electron exchange. Couple...

Enhancing Catalytic Activity of Titanium Oxide in Lithium–Sulfur Batteries by Band Engineering