Physics

Quantum dot

Nanotechnology

Nanocrystal

Organic chemistry

Crystallography

Photon upconversion

Perovskite (structure)

Chemical physics

Halide

Inorganic chemistry

Chemistry

Materials science

Spectroscopy

Quantum mechanics

Optoelectronics

Photochemistry

Ultrafast laser spectroscopy

Journal of the American Chemical Society

The spectral properties of lead halide perovskite nanocrystals (NCs) can be engineered by tuning either their sizes via the quantum confinement effect or their compositions using anion and/or cation exchange. To date, the latter is more frequently adopted, primarily because of the ease of ion exchange for lead halide perovskites, making the quantum confinement effect seemingly redundant for perovskite NCs. Here we report that quantum confinement is required for triplet energy transfer (TET) from perovskite NCs to polycyclic aromatic hydrocarbons (PAHs). Static and transient spectroscopy measurements on CsPbBr3 NC-pyrene hybrids showed that efficient TET occurred only for small-sized, quantum-confined CsPbBr3 NCs. The influences of the size-dependent driving force and spectral overlap on the TET rate were found to be negligible. Instead, the TET rate scaled linearly with carrier probability density at the NC surface, consistent with a Dexter-type TET mechanism requiring wave function exchange between the NC donors and pyrene acceptors. Efficient TET funnels the excitation energy generated in strongly light-absorbing perovskite NCs into long-lived triplets in PAHs, which may find broad applications such as photon upconversion and photoredox catalysis.

Triplet Energy Transfer from CsPbBr<sub>3</sub> Nanocrystals Enabled by Quantum Confinement

Triplet Energy Transfer from CsPbBr3 Nanocrystals Enabled by Quantum Confinement

Triplet Energy Transfer from CsPbBr₃ Nanocrystals Enabled by Quantum Confinement