Fullerene-Filled Liquid-Crystal Stars: A Supramolecular Click Mechanism for the Generation of Tailored Donor-Acceptor Assemblies
Abstract
Two shape-persistent star mesogens with oligo(phenylene ethenylene) arms and a phthalocyanine core-one providing free space (2) and one sterically encumbered by four fullerenes attached through spacers (3)-have been successfully synthesized. In contrast to the smaller discotic derivative 1, mesogen 2 forms a columnar liquid crystal (LC), which can only be partially aligned without π-stacking, while 3 is not an LC. Exceptionally, the 1:1 mixture...
Paper Details
Title
Fullerene-Filled Liquid-Crystal Stars: A Supramolecular Click Mechanism for the Generation of Tailored Donor-Acceptor Assemblies
Published Date
Jan 30, 2019
Journal
Volume
58
Issue
11
Pages
3610 - 3615
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