N → B Ladder Polymers Prepared by Postfunctionalization: Tuning of Electron Affinity and Evaluation as Acceptors in All-Polymer Solar Cells
Abstract
A poly(biphenylene–pyrazinylene) (PPz, Egopt = 3.10 eV) and a head-to-tail regioregular polypyridine (rr-P4Py, Egopt = 3.25 eV) equipped with 1-alkenyl side chains have been prepared and postfunctionalized by hydroboration with different hydroboranes (9H-BBN, (C6F5)2B-H (BPF-H), Cl2B-H) to give the corresponding ladder polymers featuring intramolecular coordinative N → B bonds. Characterization of the optical and electrochemical properties of...
Paper Details
Title
N → B Ladder Polymers Prepared by Postfunctionalization: Tuning of Electron Affinity and Evaluation as Acceptors in All-Polymer Solar Cells
Published Date
Jan 24, 2019
Journal
Volume
52
Issue
3
Pages
1013 - 1024
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