Copper‐Catalyzed Sequential C(sp2)/C(sp3)−H Amination of 2‐Vinylanilines with N‐Fluorobenzenesulfonimide
Abstract
An oxidative C−H diamination of 2‐vinylanilines with N ‐fluorobenzenesulfonimide (NFSI) was developed for the efficient synthesis of indole frameworks. The reaction proceeded via sequential intra‐/intermolecular diamination of C( sp 2 )−H and C( sp 3 )−H bond, incorporating one nitrogen from the substrate and the other nitrogen from the NFSI. magnified...
Paper Details
Title
Copper‐Catalyzed Sequential C(sp2)/C(sp3)−H Amination of 2‐Vinylanilines with N‐Fluorobenzenesulfonimide
Published Date
Feb 20, 2019
Volume
361
Issue
8
Pages
1771 - 1776
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