High Li+ and Mg2+ Conductivity in a Cu-Azolate Metal–Organic Framework
Volume: 141, Issue: 10, Pages: 4422 - 4427
Published: Feb 18, 2019
Abstract
A Cu-azolate metal-organic framework (MOF) uptakes stoichiometric loadings of Groups 1 and 2 metal halides, demonstrating efficient reversible release and reincorporation of immobilized anions within the framework. Ion-pairing interactions lead to anion-dependent Li+ and Mg2+ transport in Cu4(ttpm)2·0.6CuCl2, whose high surface area affords a high density of uniformly distributed mobile metal cations and halide binding sites. The ability to...
Paper Details
Title
High Li+ and Mg2+ Conductivity in a Cu-Azolate Metal–Organic Framework
Published Date
Feb 18, 2019
Volume
141
Issue
10
Pages
4422 - 4427
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