Hypatulone A, a Homoadamantane-Type Acylphloroglucinol with an Intricately Caged Core from Hypericum patulum
Abstract
Hypatulone A (1), an acylphloroglucinol possessing an unprecedented homoadamantane architecture based on a tricyclo-[4.3.1.13,8]-undecane core and a unique 5/5/7/6/6 pentacyclic ring system, together with its biogenetic precursor hyperbeanol B (2), was isolated from Hypericum patulum. The structure of 1 was elucidated by extensive spectroscopic analysis and electronic circular dichroism calculation. Its plausible biosynthetic pathway via...
Paper Details
Title
Hypatulone A, a Homoadamantane-Type Acylphloroglucinol with an Intricately Caged Core from Hypericum patulum
Published Date
Dec 10, 2018
Journal
Volume
20
Issue
24
Pages
7953 - 7956
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