Absolute molar mass determination in mixed solvents. 1. Solving for the SEC/MALS/DRI “trivial” case

Volume: 1053, Pages: 186 - 195
Published: Apr 1, 2019
Abstract
Size-exclusion chromatography (SEC) with on-line static light scattering, specifically multi-angle static light scattering (MALS), and differential refractometry (DRI) detection remains the premier method by which to determine absolute, calibrant-independent molar masses of polymers. The method is restricted to the use of either neat solvents or solvents with a small amount of additive. In mixed solvents, preferential solvation (i.e., the...
Paper Details
Title
Absolute molar mass determination in mixed solvents. 1. Solving for the SEC/MALS/DRI “trivial” case
Published Date
Apr 1, 2019
Volume
1053
Pages
186 - 195
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