Chemistry

Materials science

Chromatography

Physics

Electrode

Anode

Two-phase flow

Mechanics

Bubble

Flow (mathematics)

Electrolyte

Analytical Chemistry (journal)

Physical chemistry

Volumetric flow rate

Flow visualization

International Journal of Hydrogen Energy

Understanding gas evolution and two-phase flow behaviour are critical for performance optimization of polymer electrolyte membrane water electrolysers (PEMWEs), particularly at high current densities. This study investigates the gas-bubble dynamics and two-phase flow behaviour in the anode flow-field of a PEMWE under different operating conditions using high-speed optical imaging and relates the results to the electrochemical performance. Two types of anode flow-field designs were investigated, the single serpentine flow-field (SSFF) and parallel flow-field (PFF). The results show that the PFF design yielded a higher cell performance than the SSFF design at identical operating conditions. Optical visualization shows a strong relationship between the flow path length and the length of gas slugs produced, which in turn influences the flow regime of operation. Longer flow path length in the SSFF results in annular flow regime at a high current density which degrades cell performance. The annular flow regime was absent in the PFF design. It was found the effect of flow rate on performance depends strongly on operating temperature in both flow patterns. Results of this study indicate that long channel length promotes gas accumulation and channel-blocking which degrades performance in PEMWEs.

Two-phase flow behaviour and performance of polymer electrolyte membrane electrolysers: Electrochemical and optical characterisation