Form II to I transformation of polybutene-1 and copolymer of butene-1 and ethylene: A role of amorphous phase
Abstract
Polymorphic transformation from the form II to form I crystal was investigated for isotactic polybutene-1 (PB) and butene-1/ethylene copolymers (PBE) with differential scanning calorimetry (DSC) and dielectric response spectroscopy (DRS). DRS detected the so-called α relaxation of segments within the amorphous phase, and DSC traced a degree of form II to I transformation with time. It turned out that incorporation of the ethylene comonomers in...
Paper Details
Title
Form II to I transformation of polybutene-1 and copolymer of butene-1 and ethylene: A role of amorphous phase
Published Date
Aug 1, 2018
Journal
Volume
149
Pages
146 - 153
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