Synthesis of zincphthalocyanine-based conjugated microporous polymers with rigid-linker as novel and green heterogeneous photocatalysts

The novel zincphthalocyanine-based conjugated microporous polymers with rigid-linker (α-ZnPc-CMP and β-ZnPc-CMP) were synthesized by copolymerization of zinc phthalocyanine (ZnPc) and 4, 6-diaminoresorcinol dihydrochloride (DADHC). The α-ZnPc-CMP and β-ZnPc-CMP were utilized as heterogeneous photocatalysts to degrade Rhodamine B (RhB) in aqueous solution. It is the first time for MPc-based CMPs used as heterogeneous photocatalysts for...