Optics

Physics

Microstrip

Phosphor

Chirality (physics)

Luminescence

OLED

Circular polarization

Nanotechnology

Organic chemistry

Chemistry

Materials science

Quantum efficiency

Nambu–Jona-Lasinio model

Aggregation-induced emission

Layer (electronics)

Electroluminescence

Molecule

Optoelectronics

Chiral symmetry breaking

Doping

Quantum mechanics

Intramolecular force

Photochemistry

Quark

Fluorescence

Advanced Functional Materials

Development of highly efficient circularly polarized organic light-emitting diodes (CPOLEDs) has gained increasing interest as they show improved luminous efficiency and high contract 3D images in OLED displays. In this work, a series of binaphthalene-containing luminogenic enantiomers with aggregation-induced emission (AIE) and delayed fluorescence properties is designed and synthesized. These molecules can emit from green to red light depending on the solvent polarity due to the twisted intramolecular charge transfer effect. However, their solid powders show bright light emissions, demonstrating a phenomenon of AIE. All the molecules exhibit Cotton effects and circularly polarized luminescence in toluene solution and films. Multilayer CPOLEDs using the doped and neat films of the molecules as emitting layers are fabricated, which exhibit high external quantum efficiency of up to 9.3% and 3.5% and electroluminescence dissymmetry factor (gEL) of up to +0.026/−0.021 and +0.06/−0.06, respectively. Compared with doped CPOLEDs, the nondoped ones show higher gEL and much smaller current efficiency roll-off due to the stronger AIE effect. By altering the donor unit, the electroluminescence maximum of the doped film can vary from 493 to 571 nm. As far as it is known, this is the first example of efficient CPOLEDs based on small chiral organic molecules.

Highly Efficient Circularly Polarized Electroluminescence from Aggregation-Induced Emission Luminogens with Amplified Chirality and Delayed Fluorescence