Visible-Light-Enabled Preparation of Palladium Nanoparticles and Application as Catalysts for Suzuki–Miyaura Coupling
Abstract
Silyl ketones were used for the preparation of palladium nanoparticles (PdNPs) starting with Pd(OAc)2 in dimethylformamide under irradiation with a visible light-emitting diode (LED). Variation of the silyl ketone structure allowed adjustment of the PdNP diameter (1.9 or 5.2 nm). The in situ-formed PdNPs were further stabilized with polyvinylpyrrolidone and then applied as recyclable catalysts in the Suzuki-Miyaura coupling of arylboronic acids...
Paper Details
Title
Visible-Light-Enabled Preparation of Palladium Nanoparticles and Application as Catalysts for Suzuki–Miyaura Coupling
Published Date
Jan 18, 2018
Journal
Volume
20
Issue
3
Pages
752 - 755
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