Methodology for the Absolute Configuration Determination of Epoxythymols Using the Constituents of Ageratina glabrata
Abstract
A methodology to determine the enantiomeric excess and the absolute configuration (AC) of natural epoxythymols was developed and tested using five constituents of Ageratina glabrata. The methodology is based on enantiomeric purity determination employing 1,1′-bi-2-naphthol (BINOL) as a chiral solvating agent combined with vibrational circular dichroism (VCD) measurements and calculations. The conformational searching included an extensive Monte...
Paper Details
Title
Methodology for the Absolute Configuration Determination of Epoxythymols Using the Constituents of Ageratina glabrata
Published Date
Dec 26, 2017
Journal
Volume
81
Issue
1
Pages
63 - 71
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