Free Surface Relaxations of Star-Shaped Polymer Films
Abstract
The surface relaxation dynamics of supported star-shaped polymer thin films are shown to be slower than the bulk, persisting up to temperatures at least 50 K above the bulk glass transition temperature T_{g}^{bulk}. This behavior, exhibited by star-shaped polystyrenes with functionality f=8 arms and molecular weights per arm M_{arm}
Paper Details
Title
Free Surface Relaxations of Star-Shaped Polymer Films
Published Date
Nov 28, 2017
Journal
Volume
119
Issue
22
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