Photoresponsive Foams Generated by a Rigid Surfactant Derived from Dehydroabietic Acid

Innovation in the structure of surfactants is crucial to the construction of a surfactant-based system with intriguing properties. With dehydroabietic acid as a starting material, a nearly totally rigid azobenzene surfactant (R-azo-Na) was synthesized. The trans-R-azo-Na formed stable foams with half-lives of 636, 656, 976, and 872 min for 0.3, 1, 2, and 4 mmol·L–1 aqueous solutions, respectively. Under UV light irradiation, a fast collapse of...