Electronic Delocalization in the Radical Cations of Porphyrin Oligomer Molecular Wires.

Volume: 139, Issue: 30, Pages: 10461 - 10471
Published: Jul 24, 2017
Abstract
The radical cations of a family of π-conjugated porphyrin arrays have been investigated: linear chains of N = 1–6 porphyrins, a 6-porphyrin nanoring and a 12-porphyrin nanotube. The radical cations were generated in solution by chemical and electrochemical oxidation, and probed by vis–NIR–IR and EPR spectroscopies. The cations exhibit strong NIR bands at ∼1000 nm and 2000–5000 nm, which shift to longer wavelength with increasing oligomer length....
Paper Details
Title
Electronic Delocalization in the Radical Cations of Porphyrin Oligomer Molecular Wires.
Published Date
Jul 24, 2017
Volume
139
Issue
30
Pages
10461 - 10471
Citation AnalysisPro
  • Scinapse’s Top 10 Citation Journals & Affiliations graph reveals the quality and authenticity of citations received by a paper.
  • Discover whether citations have been inflated due to self-citations, or if citations include institutional bias.