Anion- and Solvent-Induced Rotary Dynamics and Sensing in a Perylene Diimide [3]Catenane

Volume: 139, Issue: 26, Pages: 9026 - 9037
Published: Jun 7, 2017
Abstract
A novel dynamic [3]catenane consisting of a large four-station central macrocycle which incorporates a bay tetrachloro-functionalized perylene diimide (PDI) unit and two triazolium anion-binding motifs, mechanically bonded with two smaller isophthalamide-containing macrocycles, is constructed using an anion template synthetic methodology. Proton NMR, electronic absorption, and fluorescence emission spectroscopies together with molecular dynamics...
Paper Details
Title
Anion- and Solvent-Induced Rotary Dynamics and Sensing in a Perylene Diimide [3]Catenane
Published Date
Jun 7, 2017
Volume
139
Issue
26
Pages
9026 - 9037
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