Enantioselective, intermolecular benzylic C–H amination catalysed by an engineered iron-haem enzyme
Abstract
C–H bonds are ubiquitous structural units of organic molecules. Although these bonds are generally considered to be chemically inert, the recent emergence of methods for C–H functionalization promises to transform the way synthetic chemistry is performed. The intermolecular amination of C–H bonds represents a particularly desirable and challenging transformation for which no efficient, highly selective, and renewable catalysts exist. Here we...
Paper Details
Title
Enantioselective, intermolecular benzylic C–H amination catalysed by an engineered iron-haem enzyme
Published Date
May 29, 2017
Journal
Volume
9
Issue
7
Pages
629 - 634
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Notes
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