One-Pot Synthesis and Characterization of Polyrotaxane–Silica Hybrid Aerogel

A novel kind of polyrotaxane-silica hybrid aerogel is successfully prepared via one-pot sol-gel synthesis in this work. The polyrotaxane can chemically interpenetrate with Si particles homogeneously in nanoscale, so as to shorten the gelation time and construct a flexible and mechanically strong skeleton. The supramolecular effect ascribable to the sliding motion of cyclic components in polyrotaxane is introduced into the hybrid aerogel for the...