Porphyrin Donor and Tunable Push–Pull Acceptor Conjugates—Experimental Investigation of Marcus Theory

Volume: 23, Issue: 26, Pages: 6357 - 6369
Published: May 5, 2017
Abstract
We report on a series of electron donor-acceptor conjugates incorporating a ZnII -porphyrin-based electron donor and a variety of non-conjugated rigid linkers connecting to push-pull chromophores as electron acceptors. The electron acceptors comprize multicyanobutadienes or extended tetracyanoquinodimethane analogues with first reduction potentials ranging from -1.67 to -0.23 V vs. Fc+ /Fc in CH2 Cl2 , which are accessible through a final-step...
Paper Details
Title
Porphyrin Donor and Tunable Push–Pull Acceptor Conjugates—Experimental Investigation of Marcus Theory
Published Date
May 5, 2017
Volume
23
Issue
26
Pages
6357 - 6369
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