Photo-induced oxidant-free oxidative C–H/N–H cross-coupling between arenes and azoles
Abstract
Direct cross-coupling between simple arenes and heterocyclic amines under mild conditions is undoubtedly important for C–N bonds construction. Selective C(sp2)-H amination is more valuable. Herein we show a selective C(sp2)-H amination of arenes (alkyl-substituted benzenes, biphenyl and anisole derivatives) accompanied by hydrogen evolution by using heterocyclic azoles as nitrogen sources. The reaction is selective for C(sp2)-H bonds, providing...
Paper Details
Title
Photo-induced oxidant-free oxidative C–H/N–H cross-coupling between arenes and azoles
Published Date
Feb 1, 2017
Journal
Volume
8
Issue
1
Pages
14226 - 14226
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