Fast Triplet Formation via Singlet Exciton Fission in a Covalent Perylenediimide-β-apocarotene Dyad Aggregate.

Volume: 119, Issue: 22, Pages: 5587 - 5596
Published: May 26, 2015
Abstract
A covalent dyad was synthesized in which perylene-3,4,:9:10-bis(dicarboximide) (PDI) is linked to β-apocarotene (Car) using a biphenyl spacer. The dyad is monomeric in toluene and forms a solution aggregate in methylcyclohexane (MCH). Using femtosecond transient absorption (fsTA) spectroscopy, the monomeric dyad and its aggregates were studied both in solution and in thin films. In toluene, photoexcitation at 530 nm preferentially excites PDI,...
Paper Details
Title
Fast Triplet Formation via Singlet Exciton Fission in a Covalent Perylenediimide-β-apocarotene Dyad Aggregate.
Published Date
May 26, 2015
Volume
119
Issue
22
Pages
5587 - 5596
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