Controlled Synthesis of Heterogeneous Metal–Titania Nanostructures and Their Applications

We describe a new synthetic approach to heterogeneous metal-TiO(2) nanomaterials based on conversion of Ti(3+) to hydrous TiO(2) occurring uniquely on the nanostructured metallic surfaces such as Pt, Au, and Ni nanowires and nanoparticles. The TiO(2) growth mechanism was studied by designing an electrochemical cell. A variety of heterogeneous metal-TiO(2) nanostructures, such as segmented metal-TiO(2) nanowires, core-shell metal-TiO(2)...