Synthesis of cycloalkyl substituted purine nucleosides via a metal-free radical route
Abstract
An efficient route to synthesize cycloalkyl substituted purine nucleosides was developed. This metal-free C-H activation was accomplished by a tBuOOtBu initiated radical reaction. By adjusting the amount of tBuOOtBu and reaction time, the selective synthesis of C6-monocycloalkyl or C6,C8-dicycloalkyl substituted purine nucleosides could be realized. Furthermore, uracil and related nucleosides were also suitable substrates, giving the...
Paper Details
Title
Synthesis of cycloalkyl substituted purine nucleosides via a metal-free radical route
Published Date
Jan 1, 2016
Volume
14
Issue
18
Pages
4189 - 4193
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