Extended hypervalent E′⋯E–E⋯E′ 4c–6e (E, E′ = Se, S) interactions: structure, stability and reactivity of 1-(8-PhE′C10H6)EE(C10H6E′Ph-8′)-1′

Volume: 32, Issue: 11, Pages: 1881 - 1889
Published: Nov 1, 2008
Abstract
The structure, stability and reactivity of E′⋯E–E⋯E′ (E2E′2) 4c–6e are examined employing naphthalene 1,8-positions in 1-(8-PhE′C10H6)EE(C10H6E′Ph-8′)-1′ [1 (E = Se, E′ = S), 2 (E = S, E′ = Se), 3 (E = E′ = Se) and 4 (E = E′ = S)], together with 1-C10H7EEC10H7-1′ [5 (E = Se) and 6 (E = S)]. Linear alignments of four Se2S2 atoms in 1 and 2 are confirmed by the X-ray analysis. 1 was not reduced by sodium borohydride, whereas 2 was, contrary to the...
Paper Details
Title
Extended hypervalent E′⋯E–E⋯E′ 4c–6e (E, E′ = Se, S) interactions: structure, stability and reactivity of 1-(8-PhE′C10H6)EE(C10H6E′Ph-8′)-1′
Published Date
Nov 1, 2008
Volume
32
Issue
11
Pages
1881 - 1889
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