Catalytic coupling of N-benzylic sulfonamides with silylated nucleophiles at room temperature
Abstract
In the presence of 2–10 mol% of Tf2NH, a range of N-benzylic sulfonamides smoothly react with allylic, propargylic, benzylic, or hydrido silanes at room temperature via sp3 carbon–nitrogen bond cleavage to afford structurally diverse products in moderate to excellent yields and with high chemo- and...
Paper Details
Title
Catalytic coupling of N-benzylic sulfonamides with silylated nucleophiles at room temperature
Published Date
Jan 1, 2010
Journal
Volume
46
Issue
33
Pages
6180 - 6180
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