Basic ionic liquids based on monoquaternized 1,4-diazobicyclo[2.2.2]octane (dabco) and dicyanamide anion: Physicochemical and solvent properties
Abstract
In this paper, we report on the synthesis and application of monosubstituted diaza - bicyclo(2.2.2)octane (dabco) cations associated with a basic anion, dicyanamide. Key prop- erties of these salts—phase transitions, density, and conductivity—were measured and com- pared to those of other common ionic liquids (ILs). Moreover, solvatochromic dyes were used to assess their solvation properties. The Heck cross-coupling reaction was evaluated in...
Paper Details
Title
Basic ionic liquids based on monoquaternized 1,4-diazobicyclo[2.2.2]octane (dabco) and dicyanamide anion: Physicochemical and solvent properties
Published Date
Oct 31, 2009
Journal
Volume
81
Issue
11
Pages
2035 - 2043
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