Developing Conjugated Polymers with High Electron Affinity by Replacing a C ? C Unit with a B←N Unit

Volume: 54, Issue: 12, Pages: 3648 - 3652
Published: Mar 16, 2015
Abstract
The key parameters of conjugated polymers are lowest unoccupied molecular orbital (LUMO) and highest occupied molecular orbital (HOMO) energy levels. Few approaches can simultaneously lower LUMO and HOMO energy levels of conjugated polymers to a large extent (>0.5 eV). Disclosed herein is a novel strategy to decrease both LUMO and HOMO energy levels of conjugated polymers by about 0.6 eV through replacement of a C-C unit by a B <- N unit. The...
Paper Details
Title
Developing Conjugated Polymers with High Electron Affinity by Replacing a C ? C Unit with a B←N Unit
Published Date
Mar 16, 2015
Volume
54
Issue
12
Pages
3648 - 3652
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