Sub‐Picosecond Singlet Exciton Fission in Cyano‐Substituted Diaryltetracenes
Volume: 54, Issue: 30, Pages: 8679 - 8683
Published: Jun 10, 2015
Abstract
Thin films of 5,11-dicyano-6,12-diphenyltetracene (TcCN) have been studied for their ability to undergo singlet exciton fission (SF). Functionalization of tetracene with cyano substituents yields a more stable chromophore with favorable energetics for exoergic SF (2E(T1)-E(S1)=-0.17 eV), where S1 and T1 are singlet and triplet excitons, respectively. As a result of tuning the triplet-state energy, SF is faster in TcCN relative to the...
Paper Details
Title
Sub‐Picosecond Singlet Exciton Fission in Cyano‐Substituted Diaryltetracenes
Published Date
Jun 10, 2015
Volume
54
Issue
30
Pages
8679 - 8683
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