Synthesis of biodegradable copolymers with low‐toxicity zirconium compounds. V. Multiblock and random copolymers of L ‐lactide with trimethylene carbonate obtained in copolymerizations initiated with zirconium(IV) acetylacetonate
Abstract
Using zirconium(IV) acetylacetonate as an initiator of lactide/trimethylene carbonate copolymerization allowed us to obtain high‐molecular‐weight copolymers with high efficiency. The reactivity ratios of the comonomers were 13.0 for lactide and 0.53 for trimethylene carbonate. Despite the large differences between the values of the reactivity ratios, copolymers with randomized chain structures were obtained. This phenomenon occurred as a result...
Paper Details
Title
Synthesis of biodegradable copolymers with low‐toxicity zirconium compounds. V. Multiblock and random copolymers of L ‐lactide with trimethylene carbonate obtained in copolymerizations initiated with zirconium(IV) acetylacetonate
Published Date
Mar 27, 2006
Volume
44
Issue
10
Pages
3184 - 3201
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