Mechanisms of catalytic cleavage of benzyl phenyl ether in aqueous and apolar phases

Volume: 311, Pages: 41 - 51
Published: Mar 1, 2014
Abstract
null null Catalytic pathways for the cleavage of ether bonds in benzyl phenyl ether (BPE) in liquid phase using Ni- and zeolite-based catalysts are explored. In the absence of catalysts, the C−O bond is selectively cleaved in water by hydrolysis, forming phenol and benzyl alcohol as intermediates, followed by alkylation. The hydronium ions catalyzing the reactions are provided by the dissociation of water at 523 K. Upon addition of HZSM-5, rates...
Paper Details
Title
Mechanisms of catalytic cleavage of benzyl phenyl ether in aqueous and apolar phases
Published Date
Mar 1, 2014
Volume
311
Pages
41 - 51
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