Kinetic study of RuIII -catalyzed polymerization of methylmethacrylate initiated with n -butylamine in the presence of carbon tetrachloride by a charge-transfer mechanism
Volume: 43, Issue: 2, Pages: 70 - 77
Published: Nov 12, 2010
Abstract
Ruthenium trichloride (RuCl3 or RuIII) catalyzed polymerization of methylmethacrylate (MMA) initiated with n-butylamine (BA) in the presence of carbon tetrachloride (CCl4) by a charge-transfer mechanism has been investigated in a dimethylsulfoxide (DMSO) medium by employing a dilatometric technique at 60°C. The rate of polymerization (Rp) has been obtained under the conditions [CCl4]/[BA] ⩽ 1 and [CCl4]/[BA] ⩾ 1. The kinetic data indicate the...
Paper Details
Title
Kinetic study of RuIII -catalyzed polymerization of methylmethacrylate initiated with n -butylamine in the presence of carbon tetrachloride by a charge-transfer mechanism
Published Date
Nov 12, 2010
Volume
43
Issue
2
Pages
70 - 77
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