Room Temperature, Metal-Free Synthesis of Diaryl Ethers with Use of Diaryliodonium Salts
Abstract
A fast, high-yielding synthesis of diaryl ethers with use of mild and metal-free conditions has been developed. The scope includes bulky ortho-substituted diaryl ethers, which are difficult to obtain by metal-catalyzed protocols. Halo-substituents, racemization-prone amino acid derivatives, and heteroaromatics are also tolerated. The methodology is expected to be of high utility in the synthesis of complex molecules and in the pharmaceutical...
Paper Details
Title
Room Temperature, Metal-Free Synthesis of Diaryl Ethers with Use of Diaryliodonium Salts
Published Date
Feb 14, 2011
Journal
Volume
13
Issue
6
Pages
1552 - 1555
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