Crystallization and thermal properties of biodegradable polyurethanes based on poly[(R)‐3‐hydroxybutyrate] and their composites with chitin whiskers
Abstract
A series of biodegradable polyurethanes (PUs) were synthesized from hydroxylated bacterial poly[(R)‐3‐hydroxybutyrate], P[(R)‐HB]‐diol, as crystallizable hard segment and hydroxyl‐terminated synthetic poly[(R,S)‐3‐hydroxybutyrate), P[(R,S)‐HB]‐diol, as an amorphous soft segment, using 1,6‐hexamethylene diisocyanate, as non‐toxic connecting agent. The P[(R)‐HB] content was varied from 30 to 70 wt %. The resulting copolymers were characterized by...
Paper Details
Title
Crystallization and thermal properties of biodegradable polyurethanes based on poly[(R)‐3‐hydroxybutyrate] and their composites with chitin whiskers
Published Date
Apr 14, 2014
Volume
131
Issue
18
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