Chemisorption on semiconductors: The role of quantum corrections on the space charge regions in multiple dimensions
Abstract
The chemisorption of O2 on nanoscale n-doped CdS semiconductors is computed in terms of a Wolkenstein isotherm coupled to the Schrödinger Poisson equation. Present numerical results show the dependence of the chemisorbed charge and the differential capacitance on oxygen partial pressure. A comparison against the classical Poisson-Boltzmann approach shows a higher chemisorbed charge in the quantum model, but a greater differential capacitance in...
Paper Details
Title
Chemisorption on semiconductors: The role of quantum corrections on the space charge regions in multiple dimensions
Published Date
Apr 30, 2012
Journal
Volume
100
Issue
18
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