Mechanism study of enhanced electrochemical performance of ZrO2-coated LiCoO2 in high voltage region
Abstract
In this study, the mechanism of enhanced performance of ZrO2-coated LiCoO2 especially at high potential range is systematically investigated. Firstly, when overcharging to 4.5 V (higher than 4.2 V, the normal cutoff charging potential), phase transformation from H1 to H2 takes place with less volume expansion for ZrO2-coated LiCoO2 (1.2% and 2.2% for as-received one). EIS analysis indicates the growth of interfacial impedance during...
Paper Details
Title
Mechanism study of enhanced electrochemical performance of ZrO2-coated LiCoO2 in high voltage region
Published Date
Jul 1, 2010
Journal
Volume
195
Issue
13
Pages
4255 - 4265
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