Cross-linking in polypyrrole and poly(N-methylpyrrole): Comparative experimental and theoretical studies
Abstract
A comparative study about cross-linking in electrogenerated polypyrrole and poly( N -methylpyrrole) is presented. Experimental studies on polymer films prepared under a constant potential of 1.4 V but considering different polymerization times as well as quantum mechanical calculations on model oligomers indicated that cross-linking is very low in polypyrrole, while cross-links are frequently formed by poly( N -methylpyrrole) chains. These...
Paper Details
Title
Cross-linking in polypyrrole and poly(N-methylpyrrole): Comparative experimental and theoretical studies
DOI
Published Date
Feb 1, 2008
Journal
Volume
49
Issue
4
Pages
1066 - 1075
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