High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO 2 Capture
Abstract
A high-throughput protocol was developed for the synthesis of zeolitic imidazolate frameworks (ZIFs). Twenty-five different ZIF crystals were synthesized from only 9600 microreactions of either zinc(II)/cobalt(II) and imidazolate/imidazolate-type linkers. All of the ZIF structures have tetrahedral frameworks: 10 of which have two different links (heterolinks), 16 of which are previously unobserved compositions and structures, and 5 of which have...
Paper Details
Title
High-Throughput Synthesis of Zeolitic Imidazolate Frameworks and Application to CO 2 Capture
Published Date
Feb 15, 2008
Journal
Volume
319
Issue
5865
Pages
939 - 943
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