Role of p(Z)–π(Ar/Nap) conjugation in structures of 1-(arylchalcogena)naphthalenes for Z = Te versus Se, S and O: experimental and theoretical investigations
Abstract
Magnitudes of the p(Z)–π(Ar/Nap) conjugation were evaluated for 1-(arylchalcogena)naphthalenes (1-(ArZ)Nap, 1-(p-YC6H4Z)C10H7; 1 (Z = Te), 2 (Se), 3 (S) and 4 (O)). Structures of 1 were determined by X-ray analysis for Y = NMe2 (b), OMe (c) and CN (i). For 1b and 1c that have electron donating Y, the Z–CAr bond is located on the naphthyl plane with Z–CNap being perpendicular to the aryl plane, which we define as (B: pd). On the other hand, the...
Paper Details
Title
Role of p(Z)–π(Ar/Nap) conjugation in structures of 1-(arylchalcogena)naphthalenes for Z = Te versus Se, S and O: experimental and theoretical investigations
Published Date
Jun 6, 2012
Journal
Volume
41
Issue
25
Pages
7485 - 7497
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