Multiblock copolymers of L-lactide and trimethylene carbonate.
Abstract
Sequential copolymerizations of trimethylene carbonate (TMC) and l-lactide (LLA) were performed with 2,2-dibutyl-2-stanna-1,3-oxepane as a bifunctional cyclic initiator. The block lengths were varied via the monomer/initiator and via the TMC/l-lactide ratio. The cyclic triblock copolymers were transformed in situ into multiblock copolymers by ring-opening polycondensation with sebacoyl chloride. The chemical compositions of the block copolymers...
Paper Details
Title
Multiblock copolymers of L-lactide and trimethylene carbonate.
Published Date
Jan 1, 2005
Journal
Volume
6
Issue
1
Pages
439 - 446
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Notes
History