Electrochemical Polarization I . A Theoretical Analysis of the Shape of Polarization Curves

Volume: 104, Issue: 1, Pages: 56 - 63
Published: Jan 1, 1957
Abstract
At low overvoltage values, deviations from Tafel behavior for a noncorroding electrode are due primarily to the reverse reaction of the oxidation‐reduction system, and at high overvoltages to concentration and/or resistance polarization. It is shown further that the practice of placing straight lines through a few experimental points is extremely hazardous, while the indiscriminate introduction of breaks is contrary to the electrode kinetics...
Paper Details
Title
Electrochemical Polarization I . A Theoretical Analysis of the Shape of Polarization Curves
Published Date
Jan 1, 1957
Volume
104
Issue
1
Pages
56 - 63
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