Long Zheng
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#1Long Zheng (Northeast Normal University)
#2Zhanjing Wang (Northeast Normal University)
Last. Yongquan Ning (Northeast Normal University)H-Index: 8
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We report herein the first example of the N3 radical-mediated azidosulfonylation of alkynes, affording the β-azidovinyl sulfone products with a broad substrate scope, excellent functional group compatibility, and high yield. DFT calculations suggest that the mechanism of the reaction proceeds through an unprecedented sequential N3 radical addition and sulfonyl radical coupling pathway.
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