Mao Minoura
Rikkyo University
Crystal structureReactivity (chemistry)Medicinal chemistryOrganic chemistryInorganic chemistryChemistryPolymer chemistrySteric effectsCombinatorial chemistryDynamic stereochemistryMethyleneAlkylRing (chemistry)Group (periodic table)MoleculeReagentTelluriumMetalSeleniumRegioselectivityNuclear magnetic resonance spectroscopyDouble bondStereochemistryPhotochemistryCrystallographyLigandHydrolysisHypervalent molecule
102Publications
15H-index
698Citations
Publications 96
Newest
#1Toshiaki MuraiH-Index: 30
Last. Mao MinouraH-Index: 15
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Organophosphorus compounds with stereogenic phosphorus and carbon atoms have received increasing attention. In this regards, primary phosphines with a stereogenic carbon atom adjacent to the phosphorus atom were synthesized by the reduction in phosphonates and phosphonoselenoates with a binaphthyl group. Their oxidized products, i.e., phosphine oxides with a stereogenic tetrasubstituted carbon atom, were found to undergo BEt3-mediated radical addition to cyclohexene to give P-stereogenic seconda...
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#1Ryohei Nishino (Rikkyo University)H-Index: 1
#2Mao Minoura (Rikkyo University)H-Index: 15
Dialkyl-diphosphenes and -distibenes of the type RTrp*2E2 (E = P, Sb; R = H, n-Pr) were synthesized and isolated using the steric protection of extended triptycyl groups (Trp*). The solubility of t...
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#1Yuna Satoh (Niigata University)H-Index: 1
#2Yutaro Fujita (Niigata University)
Last. Yoshihiro Matano (Niigata University)H-Index: 41
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This work reports a series of covalently linked hybrids comprising 5,10,15,20-tetraaryl-5,15-diazaporphyrinoids (M-TADAP; M = Ni, Zn, Cu) and amines. M-TADAP-amine hybrids were prepared via the metal-templated cyclization of the corresponding metal(II)-dipyrrin complexes and redox reactions on the DAP unit. In the UV/vis/near-IR absorption spectra of the hybrids containing an 18π-electron DAP ring, broad charge-transfer bands were observed, reflecting the electron-donating property of the para-a...
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#1Koh Sugamata (Rikkyo University)H-Index: 2
#2Sho Kobayashi (Rikkyo University)
Last. Mao Minoura (Rikkyo University)H-Index: 15
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#1Kobayashi DaiyaH-Index: 1
#2Akira HamakawaH-Index: 1
Last. Mao Minoura (Rikkyo University)H-Index: 15
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Novel metal–organic frameworks (MOFs) based on thiabendazole (TBZ) were developed. The two structurally distinct TBZ-MOFs synthesized in this study exhibited enhanced durability and a broader biocidal spectrum than either individual bioactive species (i.e., Zn2+ and TBZ). The characteristics of each TBZ-MOF are related to the coordination modes among the Zn2+ ions and ligand donors. The difference in water solubility between the two TBZ-MOFs due to the structural design allows for the controlled...
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#1Masahiro NakanoH-Index: 23
#2Nobuhiko OhtsukaH-Index: 2
Last. Mao MinouraH-Index: 15
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#1Nobuhiko Ohtsuka (Saitama University)H-Index: 2
#2Masahiro Nakano (Kanazawa University)H-Index: 8
Last. Mao MinouraH-Index: 15
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A Naphthalene diimide (NDI)-incorporated helical thienoacene was developed. The compound has high electron mobility (1.4 cm2 V−1 s−1) thanks to its two-dimensional π–π interaction assisted by the intermolecular C–H⋯O hydrogen bonding of the NDI moieties. Moreover, its bow-shaped π-skeleton reduces molecular fluctuation and gives the compound a thermally stable solid phase, which enables us to fabricate thermally stable organic devices.
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#1Koh Sugamata (Rikkyo University)H-Index: 2
#2Daichi Yanagisawa (Rikkyo University)H-Index: 1
Last. Mao Minoura (Rikkyo University)H-Index: 15
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The first example of an inter­penetrated methyl-modified MOF-5 with the for­mula Zn4O(DMBDC)3(DMF)2, where DMBDC2− is 2,5-di­methyl­ben­zene-1,4-di­carboxyl­ate and DMF is N,N-di­methyl­formamide (henceforth denoted as Me2MOF-5-int), namely, poly[tris­(μ4-2,5-di­methyl­benzene-1,4-di­carboxyl­ato)bis­(N,N-di­methyl­formamide)-μ4-oxido-tetra­zinc(II)], [Zn4(C10H8O4)3O(C3H7NO)2]n, has been obtained from a solvothermal synthesis of 2,5-di­methyl­benzene-1,4-dicarboxylic acid and Zn(NO3)2·6H2O in DM...
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#1Koh Sugamata (Rikkyo University)H-Index: 2
#2Chikaze Takagi (Rikkyo University)H-Index: 1
Last. Mao Minoura (Rikkyo University)H-Index: 15
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Two mixed-ligand metal-organic frameworks, [Zn2(BDHA)0.5(INA)3] (MOF-1: H2BDHA = benzene-1,4-dihydroxamic acid; HINA = isonicotinic acid) and [Co2(BDHA)0.5(INA)3(DMF)] (MOF-2), were solvothermally synthesized and fully characterized by single-crystal X-ray crystallography as well as N2, H2, and CO2 gas-sorption isotherms. The results constitute the first detailed analysis of the bonding environment around the hydroxamates in such MOFs, which are simultaneously decorated with Lewis-basic sites fr...
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#1Kazuma Kuwabara (Gidai: Gifu University)H-Index: 3
#2Yuuki Maekawa (Gidai: Gifu University)H-Index: 6
Last. Toshiaki Murai (Gidai: Gifu University)H-Index: 30
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P-Stereogenic phosphonothioates have attracted much attention due to their potent biological activities as analogs of phosphoric acids and phosphorothioates. We demonstrate here straightforward access to P-stereogenic phosphonothioates through the use of binaphthyl phosphonothioates as a chiral template. The 1st-step alcoholysis of binaphthyl phosphonothioates proceeded via a transfer of the axial chirality of a binaphthyl group to the central chirality of a phosphorus atom to give only mono-alc...
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